Electrophilic Substitution of Benzene (OCR A-Level Chemistry A): Flashcards

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Electrophilic substitution of benzene
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Characteristic reaction of benzene

Electrophilic substitution

Nitration catalyst & temp for benzene

Conc. H2SO4H_2SO_4, 50°C

Electrophile in nitration of benzene

Nitronium ion (NO2+NO_2^+)

Why halogen carrier needed for benzene halogenation

To generate electrophile (Br+Br^+ or Cl+Cl^+)

Catalyst for bromination of benzene

FeBr3FeBr_3 or AlBr3AlBr_3

Reagent in Friedel-Crafts alkylation

Haloalkane

Reagent in Friedel-Crafts acylation

Acyl chloride

Product type from Friedel-Crafts acylation

Aromatic ketone

Why benzene undergoes substitution not addition

Preserves aromatic stability

Benzene vs alkene with bromine water

Alkene decolourises; benzene doesn't (needs catalyst)

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