Carboxylic Acid Derivatives (OCR A-Level Chemistry A): Flashcards
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Define carboxylic acid derivative
Define carboxylic acid derivative
Compound that can be hydrolysed to form parent carboxylic acid
Structure of acyl group
Structure of acyl group
Four types of carboxylic acid derivatives
Four types of carboxylic acid derivatives
Esters, acyl chlorides, acid anhydrides, amides
Ester naming rule order
Ester naming rule order
Alcohol part first, then acid part
Esterification reaction conditions
Esterification reaction conditions
Heat under reflux, conc. catalyst
Alkaline hydrolysis of ester produces?
Alkaline hydrolysis of ester produces?
Carboxylate salt + alcohol (irreversible)
Reagent to prepare acyl chlorides from carboxylic acids
Reagent to prepare acyl chlorides from carboxylic acids
Thionyl chloride ()
Why are acyl chlorides highly reactive?
Why are acyl chlorides highly reactive?
Cl is good leaving group, C=O carbon is
Moles of needed per mole acyl chloride
Moles of needed per mole acyl chloride
2 moles (one forms amide, one neutralises HCl)
Shape changes in nucleophilic addition-elimination
Shape changes in nucleophilic addition-elimination
Trigonal planar → tetrahedral → trigonal planar
