Carbon-13 NMR Spectroscopy (OCR A-Level Chemistry A): Quizzes

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Carbon-13 NMR Spectroscopy
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What two pieces of info does 13^{13}C NMR provide about a molecule?

No. of C environments & types of C atoms

What reference compound is used for 13^{13}C NMR chemical shifts?

Tetramethylsilane (TMS)

What chemical shift value is assigned to TMS in 13^{13}C NMR?

δ=0\delta = 0 ppm

What is the approximate extent of the 13^{13}C NMR chemical shift scale?

220 ppm

In which range do carbonyl carbons (C=O) appear?

δ=160220\delta = 160-220 ppm

In which range do saturated C-C bonds appear?

δ=040\delta = 0-40 ppm

When are carbon atoms considered equivalent?

When symmetrically positioned in molecule

What does the number of peaks in a 13^{13}C NMR spectrum equal?

Number of different C environments

How many peaks does propanone (CH3COCH3\text{CH}_3\text{COCH}_3) show?

2 peaks

What effect does proximity to electronegative atoms have on chemical shift?

Shifts peak to higher δ\delta values

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