Carbon-13 NMR Spectroscopy (OCR A-Level Chemistry A): Flashcards

📚Flashcards
Carbon-13 NMR Spectroscopy
Sign up to keep revising.Create a free account to study more flashcards and track your progress.

Practise the cards

10 cards from this deck

Show

Reference compound in 13^{13}C NMR (δ=0\delta = 0)

TMS (tetramethylsilane)

C=O carbon shift range in 13^{13}C NMR

δ=160220\delta = 160-220 ppm

Aromatic/C=C carbon shift range

δ=110160\delta = 110-160 ppm

C-O, C-N, C-Cl, C-Br shift range

δ=4080\delta = 40-80 ppm

Saturated C-C bond shift range

δ=040\delta = 0-40 ppm

Peak count in 13^{13}C NMR shows

Number of different carbon environments

Equivalent carbon atoms definition

Same environment; symmetrically positioned

Max 13^{13}C NMR shift scale

~220 ppm

Peaks in propanone (CH3COCH3CH_3COCH_3) 13^{13}C NMR

2 (both CH3CH_3 groups equivalent)

Electronegative atom effect on C shift

Withdraws electrons; higher δ\delta (deshielding)

Join 100,000+ A-Level students studying Flashcards with us.

Select your subjects, and get access to A+ resources today.