Racemic Mixtures (AQA A-Level Chemistry): Quizzes

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Racemic Mixtures
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What is the ratio of enantiomers in a racemic mixture?

50:50

What optical property does a racemic mixture exhibit?

Optically inactive

If one enantiomer rotates light by +10+10 degrees, what does the other rotate it by in a racemate?

10-10 degrees

What is the net rotation of plane-polarised light in a racemic mixture?

00 degrees

Which compounds typically form racemic mixtures via nucleophilic addition?

Ketones and aldehydes

What is the geometry of a carbonyl group?

Planar

From which directions can a nucleophile attack a carbonyl carbon?

Top or bottom of the plane

Why does nucleophilic attack on a carbonyl produce a 50:50 mix of enantiomers?

Equal probability of attack from each side

How can optical isomers be distinguished from each other?

Through their optical activity

What problem can racemic mixtures cause in pharmaceuticals?

Reduce drug efficacy or cause side effects

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