Nucleophilic Addition (AQA A-Level Chemistry): Quizzes

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Nucleophilic Addition
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What type of reaction do aldehydes and ketones undergo with nucleophiles?

Nucleophilic addition

What is the product when an aldehyde is reduced with NaBH4NaBH_4 in aqueous solution?

Primary alcohol

What alcohol is formed when a ketone is reduced with aqueous NaBH4NaBH_4?

Secondary alcohol

Which species acts as the nucleophile in NaBH4NaBH_4 reduction reactions?

H−H^- (hydride ion)

What product forms when aldehydes react with KCNKCN followed by dilute acid?

Hydroxynitrile

Which atom in the carbonyl group is attacked by the nucleophile CN−CN^-?

δ+δ+ carbon atom

Why does CN−CN^- attack on unsymmetrical carbonyls produce a racemic mixture?

Equal attack from above or below

What is the optical activity of a racemic mixture of enantiomers?

Optically inactive

How does KCNKCN cause toxicity in the body?

Binds to Fe in cytochrome enzymes

Why is the hydroxynitrile reaction valuable in organic synthesis?

It extends the carbon chain

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