Nucleophilic Substitution (AQA A-Level Chemistry): Quizzes

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Nucleophilic Substitution
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What is a nucleophile?

Species donating lone pair of electrons

What conditions are needed for OH−OH⁻ to react with halogenoalkanes to form alcohols?

Aqueous and warm conditions

What is special about the reaction of CN−CN⁻ with halogenoalkanes?

It lengthens the carbon chain

Why is a sealed flask used for ammonia reacting with halogenoalkanes?

Ammonia would escape as gas with reflux

What is the major product when excess ammonia reacts with a halogenoalkane?

Primary amine

What happens to nitrogen in a quaternary ammonium salt?

Positively charged with no lone pair

What makes quaternary ammonium salts useful as cationic surfactants?

Charged head and hydrophobic tail

Which carbon does the nucleophile attack in halogenoalkane substitution?

Positively charged carbon with halogen

What intermediate forms when ammonia attacks an acyl chloride's carbonyl carbon?

A tetrahedral intermediate

What by-product forms when ammonia reacts with an acid anhydride?

A carboxylic acid

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