Iodine/Thiosulfate Redox Titrations (OCR A-Level Chemistry A): Quizzes

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Iodine/Thiosulfate Redox Titrations
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What product is formed when thiosulfate ions (S2O32\text{S}_2\text{O}_3^{2-}) are oxidised in this titration?

S4O62\text{S}_4\text{O}_6^{2-}

What is the mole ratio between ClO\text{ClO}^- and S2O32\text{S}_2\text{O}_3^{2-} in bleach analysis?

1 mol ClO\text{ClO}^- ≡ 2 mol S2O32\text{S}_2\text{O}_3^{2-}

When should starch indicator be added during the titration?

When solution becomes pale straw colour

What colour is observed at the end point of the titration?

Colourless

What is the mole ratio between Cu2+\text{Cu}^{2+} and S2O32\text{S}_2\text{O}_3^{2-} in copper analysis?

1 mol Cu2+\text{Cu}^{2+} ≡ 1 mol S2O32\text{S}_2\text{O}_3^{2-}

Which of these can be analysed using iodine/thiosulfate titrations?

Copper content in brass alloys

Why is hydrochloric acid added in the analysis of bleach?

To provide H+\text{H}^+ ions for the reaction

What colour does the solution turn immediately after adding starch indicator?

Deep blue-black

What precipitate forms when Cu2+\text{Cu}^{2+} reacts with excess iodide ions?

White copper(I) iodide (CuI)

What is the key requirement for an oxidising agent to be analysed by this technique?

It must oxidise I\text{I}^- to I2\text{I}_2

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