Electrolysis to extract metals (Edexcel GCSE Chemistry): Flashcards

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4.3.3 Using Electrolysis to Extract Metals
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Method to extract reactive metals from ores

Electrolysis

Primary ore of aluminium

Bauxite

Chemical formula of bauxite

Al2O3Al_2O_3 (aluminium oxide)

Compound mixed with bauxite for electrolysis

Cryolite

Why cryolite is added to bauxite

Lowers the melting point

Type of electrodes in aluminium extraction

Graphite electrodes

Ion attracted to cathode in Al extraction

Al3+Al^{3+} (aluminium ions)

Process at cathode for Al3+Al^{3+}

Gain electrons (reduction)

Cathode equation for aluminium

Al3++3eAl(l)Al^{3+} + 3e^- \rightarrow Al(l)

Why molten aluminium sinks in cell

Denser than surrounding mixture

Ion attracted to anode

O2O^{2-} (oxide ions)

Process at anode for O2O^{2-}

Lose electrons (oxidation)

Anode equation in aluminium extraction

2O2O2(g)+4e2O^{2-} \rightarrow O_2(g) + 4e^-

Element oxide ions react with at anode

Carbon (in graphite anode)

Gas from oxide ions reacting with carbon

Carbon dioxide (CO2CO_2)

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