Atom economy (Edexcel GCSE Chemistry): Revision Notes
Atom Economy
Atom economy is a measure of how much of the starting materials (reactants) end up as useful products in a chemical reaction. The higher the atom economy, the less waste is produced, making the process more efficient and environmentally friendly.
How to Calculate Atom Economy: The formula for atom economy is:
Example:
- Fermentation of Glucose:
- Suppose you're making ethanol (C₂H₅OH) from glucose (C₆H₁₂O₆).
- The Mr of ethanol is 92, and the total Mr of all products (including waste) is 180.
- Using the formula:
- So, 51% of the atoms in the reactants end up in the desired product.
- Hydration of Ethene:
- In this process, all the reactants are turned into ethanol, so the atom economy is 100%. This means no atoms are wasted, making it a very efficient reaction.
What are Theoretical Masses?
Theoretical mass is the maximum amount of product that could be formed from a given amount of reactants, assuming the reaction goes perfectly with no losses or side reactions.
How to Calculate Theoretical Mass:
- To find the theoretical mass of a product:
- Use the balanced chemical equation to see the ratio of reactants to products.
- Calculate the moles of reactants you're starting with.
- Use the mole ratio from the equation to find the moles of product you should get.
- Convert moles to grams using the relative formula mass (Mr) of the product.
Example Problem: Let's say you want to calculate the theoretical mass of water (H₂O) produced when 8 grammes of hydrogen gas (H₂) reacts with excess oxygen gas (O₂).
Step 1: Use the balanced chemical equation: The balanced equation for the reaction between hydrogen and oxygen to form water is:
This equation tells us that 2 moles of hydrogen gas react with 1 mole of oxygen gas to produce 2 moles of water.
Step 2: Calculate the moles of reactants:
- First, find the relative formula mass (Mr) of hydrogen gas (H₂):
- The atomic mass of hydrogen (H) is 1, so:
- Now, calculate the moles of hydrogen gas you have:
Step 3: Use the mole ratio:
- The balanced equation tells us that 2 moles of H₂ produce 2 moles of H₂O.
- Since we have 4 moles of H₂, and the ratio is 1:1, we will produce 4 moles of H₂O.
Step 4: Convert moles to grams:
- Find the relative formula mass (Mr) of water (H₂O):
- The atomic mass of hydrogen (H) is 1, and oxygen (O) is 16, so:
- Now, calculate the theoretical mass of water:
Final Answer:
- The theoretical mass of water produced is 72 grams.