The Process of Electrolysis (Edexcel GCSE Chemistry): Flashcards

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4.3.1 The Process of Electrolysis
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Definition of electrolysis

Uses electric current to separate ionic compound into ions

Literal meaning of 'electrolysis'

Splitting using electricity

Why ionic compound must be molten/dissolved for electrolysis

So ions are free to move, not fixed in crystal lattice

Definition of electrolyte

Ionic compound (molten/solution) with free-moving ions

Identity of anode

Positive electrode

Identity of cathode

Negative electrode

Ions attracted to cathode

Positive ions

Ions attracted to anode

Negative ions

Process occurring at cathode

Reduction (ions gain electrons)

Process occurring at anode

Oxidation (ions lose electrons)

General equation at cathode

M++eMM^+ + e^- \rightarrow M

General equation at anode

XX+eX^- \rightarrow X + e^-

Forms of discharged products

Solid sediments or gases

Purpose of inert electrodes

Don't react with electrolyte; reactions only at surface

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