11 – Standardising a Potassium Permanganate Solution (LC 2027) (Leaving Cert Chemistry): Flashcards

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11 – Standardising a Potassium Permanganate Solution
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Standardisation definition

Finding exact concentration by titrating against known standard

Standard solution

Substance of known concentration

Why ammonium iron(II) sulfate is good primary standard

Stable, doesn't absorb moisture, high molar mass

Role of acid when dissolving Fe2+\text{Fe}^{2+} crystals

Prevents oxidation of Fe2+\text{Fe}^{2+} to Fe3+\text{Fe}^{3+}

Why excess acid needed in titration

Provides H+\text{H}^+ ions for permanganate reduction

Self-indicating meaning

KMnO4\text{KMnO}_4 acts as its own indicator

End point colour in permanganate titration

Permanent faint pink colour

Autocatalysis in this titration

Reaction speeds up as Mn2+\text{Mn}^{2+} ions form

Mole ratio MnO4−\text{MnO}_4^- : Fe2+\text{Fe}^{2+}

1:5

Concordant results requirement

Should agree within 0.1 cm3\text{cm}^3

Brown precipitate indicates

Insufficient acid added

Why rinse burette with solution to be used

Prevents dilution by residual water

Why KMnO4\text{KMnO}_4 can't be made by dilution

Concentration changes over time due to decomposition

Oxidation half-equation for Fe2+\text{Fe}^{2+}

Fe2+→Fe3++e−\text{Fe}^{2+} \to \text{Fe}^{3+} + e^-

Times to invert volumetric flask

About 20 times

Explore Leaving Cert Chemistry Revision Notes by Topics

Overview of Experiments (LC 2026)

Overview of Experiments (LC 2026)

1 – Carrying Out Flame Tests (LC 2027)

1 – Carrying Out Flame Tests (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

Show more

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

Explore Leaving Cert Chemistry Model Answers by Topics

Overview of Experiments (LC 2026)

Overview of Experiments (LC 2026)

1 – Carrying Out Flame Tests (LC 2027)

1 – Carrying Out Flame Tests (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

Show more

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

Explore Leaving Cert Chemistry Quizzes by Topics

Overview of Experiments (LC 2026)

Overview of Experiments (LC 2026)

1 – Carrying Out Flame Tests (LC 2027)

1 – Carrying Out Flame Tests (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

Show more

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

Explore Leaving Cert Chemistry Exam Questions by Topics

Overview of Experiments (LC 2026)

Overview of Experiments (LC 2026)

1 – Carrying Out Flame Tests (LC 2027)

1 – Carrying Out Flame Tests (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

2 – Detecting the Presence of Anions (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

3 – Measuring the Relative Molecular Mass of a Volatile Liquid (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

Show more

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

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