13 – Standardising a Sodium Thiosulfate Solution (LC 2027) (Leaving Cert Chemistry): Flashcards

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13 – Standardising a Sodium Thiosulfate Solution
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Standardisation definition

Finding exact conc. by titrating vs known standard solution

Aim of Na2S2O3\text{Na}_2\text{S}_2\text{O}_3 standardisation

Determine exact conc. via iodine-thiosulfate titration

Products of MnO4−\text{MnO}_4^- + I−\text{I}^- reaction

Mn2+\text{Mn}^{2+}, I2\text{I}_2, H2O\text{H}_2\text{O}

I2\text{I}_2 + S2O32−\text{S}_2\text{O}_3^{2-} products

S4O62−\text{S}_4\text{O}_6^{2-} + I−\text{I}^-

Purpose of white tile

Observe colour changes clearly

Why add H2SO4\text{H}_2\text{SO}_4 to flask

Make solution acidic for permanganate reaction

Why excess KI used

Ensure complete reduction of permanganate ions

Initial solution colour (before KI)

Purple (from KMnO4\text{KMnO}_4)

Colour after KI addition

Reddish-brown (from I2\text{I}_2 formed)

When to add starch indicator

When solution becomes pale yellow

Colour immediately after starch added

Blue-black (starch-iodine complex)

End point colour in this titration

Colourless (blue-black disappears completely)

Why add starch when pale yellow, not early

Starch-I2\text{I}_2 complex more stable at low conc.

What end point indicates

All iodine has reacted with thiosulfate

Explore Leaving Cert Chemistry Revision Notes by Topics

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4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

Explore Leaving Cert Chemistry Model Answers by Topics

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4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

Explore Leaving Cert Chemistry Quizzes by Topics

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4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

Explore Leaving Cert Chemistry Exam Questions by Topics

Show more

4 – Verifying the Law of Conservation of Mass (LC 2027)

4 – Verifying the Law of Conservation of Mass (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

5 – Investigating Decreases in Concentration (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

6 – Preparing Sodium Carbonate (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

7 – Standardising a Hydrochloric Acid Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

8 – Standardising a Sodium Hydroxide Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

9 – Determining the Concentration of an Ammonia Solution (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

10 – Determining the Concentration of Ethanoic Acid in Vinegar (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

11 – Standardising a Potassium Permanganate Solution (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

12 – Determining the Percentage of Elemental Iron in an Iron Tablet (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

13 – Standardising a Sodium Thiosulfate Solution (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

14 – Investigating the Rate of Decomposition of Hydrogen Peroxide (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

15 – Investigating the Effect of Surface Area on Reaction Rates (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

16 – Studying the Effect of Concentration on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

17 – Studying the Effect of Temperature on Reaction Rate (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

18 – Investigating Effects on the State of Equilibrium (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

19 – Investigating the Heat of Combustion of Alcohols (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

20 – Determining the Enthalpy of Reaction of a Neutralisation Reaction (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

21 – Investigating Galvanic Cells (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

22 – Investigating with Inert Electrodes (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

23 – Preparing & Investigating Ethene (LC 2027)

24 – Preparing an Ester (LC 2027)

24 – Preparing an Ester (LC 2027)

25 – Preparing Soap (LC 2027)

25 – Preparing Soap (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

26 – Distinguishing Between Aldehydes and Ketones (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

27 – Synthesising & Investigating Benzoic Acid (LC 2027)

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