19 – Investigating the Heat of Combustion of Alcohols (LC 2027) (Leaving Cert Chemistry): Flashcards
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Heat of combustion definition
Heat of combustion definition
Energy released when 1 mole burns completely in oxygen
Calorimetry definition
Calorimetry definition
Technique to measure heat transfer via temp changes in water
Why is copper used for the calorimeter?
Why is copper used for the calorimeter?
Excellent heat conductor, ensures efficient heat transfer
Purpose of draught shield
Purpose of draught shield
Prevents air currents interfering with flame, improves accuracy
What type of reaction is alcohol combustion?
What type of reaction is alcohol combustion?
Exothermic (energy released to surroundings)
Heat transfer equation
Heat transfer equation
Specific heat capacity of water
Specific heat capacity of water
J kg K (or kJ kg K)
Specific heat capacity definition
Specific heat capacity definition
Heat needed to raise 1 kg of substance by 1 K
What must be stirred during the experiment?
What must be stirred during the experiment?
The water (gently, to ensure even heat distribution)
How does molecular length affect energy released?
How does molecular length affect energy released?
Longer molecules release more energy (more bonds to break)
Main assumption in this experiment
Main assumption in this experiment
All heat from burning alcohol goes into heating the water
Major source of error in experiment
Major source of error in experiment
Heat loss to surroundings
Why are experimental values lower than theoretical?
Why are experimental values lower than theoretical?
Heat losses, incomplete combustion, apparatus absorption
How is mass of alcohol burned found?
How is mass of alcohol burned found?
Weigh spirit burner before and after, find difference
Energy contribution per -CH- group added
Energy contribution per -CH- group added
Approximately kJ/mol more energy release
